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Grant: Alliance Grants

University of Guelph

$718,125.00

Environmental Impact of Sulfolane: Transport, Fate and Toxicity in Freshwater

FY 2024-25

Summary
Sulfolane is an organosulfur toxic compound miscible in water and used in many industrial processes, including the Sulfinol process developed by Shell. This process is utilized to sweeten sour gas. Sulfolane has been released due to spills and improper disposal, and large plumes exist in Alberta, impacting both groundwater and surface water. Despite its presence on a number of sites, its transport and fate, as well as ecotoxicity are not fully understood. Our project focuses on understanding the transport, fate and toxicity of sulfolane to ecological receptors. Our interdisciplinary academic team involves academics expert in environmental engineering, hydrogeology, toxicology and chemistry. This team is well versed to complement our industry partners, which include the site owners (Shell), field and environmental professionals (Matrix Solutions) and ecotoxicology experts (Azimuth). Our project will achieve the following: 1) develop robust analytical methods to detect and quantify sulfolane and other co-contaminants present (such as non soluble organic solvents), enabling their temporal and spatial mapping on impacted sites; 2) elucidate the mechanisms of sulfolane transport and understand biotic and abiotic transformation of sulfolane, through integrated lab and field studies; 3) asses the ecotoxicity of sulfolane, in the presence and absence of co-contaminants. The knowledge gained during this project will enable predicting sulfolane risks in the environment, and informing site management for sites owned both by Shell and others. It may also aid in identifying suitable remedial strategies and developing improved regulation in Canada.
Program
Alliance Grants
Location
Ontario, Canada
Recipient Type
Academia
Type
Grant
Source
NSERC's Awards Data

As published

Application id
581256-2022
Name nom
Pensini, Erica E
Department département
Engineering, School of
Organization id
24
Institution établissement
University of Guelph
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2024
Competition year année de concours
2022
Award amount
718125
Program id
ALLRP
Program name en
Alliance Grants
Program name fr
Subventions Alliance
Group en
RESEARCH PARTNERSHIPS
Group fr
PARTENARIATS DE RECHERCHE
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
400
Area of application group en
Environment
Area of application group fr
Environnement
Area of application en
Environment
Area of application fr
Environnement
Research subject code
1501
Research subject group en
Environmental engineering
Research subject group fr
Génie de l'environnement
Research subject en
Water quality, pollution
Research subject fr
Qualité de l'eau, pollution
Field of research list names en
Not available
Field of research list names fr
Non disponible
Socioeconomic objective list names en
Not available
Socioeconomic objective list names fr
Non disponible
Application title
Environmental Impact of Sulfolane: Transport, Fate and Toxicity in Freshwater
Keywords
aquifer; complex fluid behavior; detection; freshwater; non aqueous phase co-contaminants; phase behaviour; sulfolane; surface water; toxicology; transport and fate
Application summary
Sulfolane is an organosulfur toxic compound miscible in water and used in many industrial processes, including the Sulfinol process developed by Shell. This process is utilized to sweeten sour gas. Sulfolane has been released due to spills and improper disposal, and large plumes exist in Alberta, impacting both groundwater and surface water. Despite its presence on a number of sites, its transport and fate, as well as ecotoxicity are not fully understood. Our project focuses on understanding the transport, fate and toxicity of sulfolane to ecological receptors. Our interdisciplinary academic team involves academics expert in environmental engineering, hydrogeology, toxicology and chemistry. This team is well versed to complement our industry partners, which include the site owners (Shell), field and environmental professionals (Matrix Solutions) and ecotoxicology experts (Azimuth). Our project will achieve the following: 1) develop robust analytical methods to detect and quantify sulfolane and other co-contaminants present (such as non soluble organic solvents), enabling their temporal and spatial mapping on impacted sites; 2) elucidate the mechanisms of sulfolane transport and understand biotic and abiotic transformation of sulfolane, through integrated lab and field studies; 3) asses the ecotoxicity of sulfolane, in the presence and absence of co-contaminants. The knowledge gained during this project will enable predicting sulfolane risks in the environment, and informing site management for sites owned both by Shell and others. It may also aid in identifying suitable remedial strategies and developing improved regulation in Canada.