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Grant: Strategic Projects - Group

University of Waterloo

$181,000.00

Metal isotope ratios as indicators of dissolved metal release and attenuation

FY 2011-12

Summary
The release of metals at mine sites, mineral processing facilities, and mine waste disposal areas can result in contamination of groundwater resources. Dissolved metals such as Cu, Ni, and Zn can migrate along the groundwater flow path, and may be attenuated by reactions with the aquifer minerals and through microbially-mediated biogeochemical reactions. Enhancing these attenuation reactions forms the basis for many in situ groundwater remediation systems. This research project will use measurements of stable isotope ratios of Cu, Ni, and Zn to determine reaction mechanisms controlling the concentrations of dissolved metals in groundwater. The research will encompass mine wastes and in situ groundwater treatment systems. The research project includes the development and implementation of emerging analytical procedures to measure the stable isotope ratios of dissolved metals, assessment of the extent of isotope fractionation in abiotic and microbially-mediated reaction systems, measurement of isotope ratios in field and laboratory systems and the development and application of numerical modelling tools to assist in the interpretation of the laboratory and field observations. The information gained from the proposed study can be used to 1) assist in the development and assessment of improved designs for waste management and site rehabilitation, and 2) inform the development of effective environmental policie. Optimization of remediation systems will lead to cost savings for companies operating in Canada and Canadian companies operating in other parts of the world. The development of more effective and efficient methods to rehabilitate metal contaminated sites potentially will allow a larger number of sites to undergo remediation, leading to an overall decrease in pollutant levels entering the environment. These improvements in the environment will benefit Canadians living near contaminated sites and ecosystems as a whole. The project will train a significant number of Canadian undergraduate students, graduate students, and postdoctoral fellows, prpearing them for significant roles in the sustainable and economic development of resources in Canada.
Program
Strategic Projects - Group
Location
Ontario, Canada
Recipient Type
Academia
Type
Grant
Source
NSERC's Awards Data

As published

Application id
413161-2011
Name nom
Blowes, David
Department département
Earth & Environmental Sciences
Organization id
33
Institution établissement
University of Waterloo
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2011
Competition year année de concours
2011
Award amount
181000
Program id
STPGP
Program nane en
Strategic Projects - Group
Program name fr
Projets stratégiques - De groupe
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
1572
Committee name en
Strategic Projects Selection Panel - Natural Resources
Committee name fr
Comité de sélection des projets stratégiques - Ressources naturelles
Area of application code
409
Area of application group en
Environment
Area of application group fr
Environnement
Area of application en
Environmental impact of economic activities (including agriculture)
Area of application fr
Effet des activités économiques sur l'environnement (y compris agriculture)
Research subject code
4201
Research subject group en
Geochemistry and geochronology
Research subject group fr
Géochimie et géochronologie
Research subject en
Environmental geochemistry
Research subject fr
Géochimie environnementale
Partie
1
Nb partie
3
Application title
Metal isotope ratios as indicators of dissolved metal release and attenuation
Keyword
NSERC
Application summary
The release of metals at mine sites, mineral processing facilities, and mine waste disposal areas can result in contamination of groundwater resources. Dissolved metals such as Cu, Ni, and Zn can migrate along the groundwater flow path, and may be attenuated by reactions with the aquifer minerals and through microbially-mediated biogeochemical reactions. Enhancing these attenuation reactions forms the basis for many in situ groundwater remediation systems. This research project will use measurements of stable isotope ratios of Cu, Ni, and Zn to determine reaction mechanisms controlling the concentrations of dissolved metals in groundwater. The research will encompass mine wastes and in situ groundwater treatment systems. The research project includes the development and implementation of emerging analytical procedures to measure the stable isotope ratios of dissolved metals, assessment of the extent of isotope fractionation in abiotic and microbially-mediated reaction systems, measurement of isotope ratios in field and laboratory systems and the development and application of numerical modelling tools to assist in the interpretation of the laboratory and field observations. The information gained from the proposed study can be used to 1) assist in the development and assessment of improved designs for waste management and site rehabilitation, and 2) inform the development of effective environmental policie. Optimization of remediation systems will lead to cost savings for companies operating in Canada and Canadian companies operating in other parts of the world. The development of more effective and efficient methods to rehabilitate metal contaminated sites potentially will allow a larger number of sites to undergo remediation, leading to an overall decrease in pollutant levels entering the environment. These improvements in the environment will benefit Canadians living near contaminated sites and ecosystems as a whole. The project will train a significant number of Canadian undergraduate students, graduate students, and postdoctoral fellows, prpearing them for significant roles in the sustainable and economic development of resources in Canada.