Grant: Applied Research and Development Grants - Level 1
Sheridan Institute of Technology and Advanced Learning
$25,000.00
Polymeric Nanofibres as a Scaffold for Nanoporous Metal Foams (NMFs) Production
FY 2017-18
Summary
Currently, the compact and large surface-area properties of nanoporous metal foams (NMFs) allow for its use in various applications such as electrodes, sensors, and filters. With the market demanding electronic devices to continue to decrease in size while increasing in performance, the ultra-compact batteries powering them will see electrodes made of NMFs as an essential component. To manufacture NMFs, a polymer scaffold, such as a sponge, is often used as the starting material. There are applications that require maximum surface area, with target pore sizes of the scaffold to be between 5 and 20µm so that the final metallic void can reach a diameter ranging from less than 3nm to 1µm. Polymer foam scaffold manufactured through conventional production methods cannot create such fine pores. A promising technology called electrospinning has the ability to produce uniform nanoporous polymer structures for the subsequent production of NMFs. Electrospinning involves the pinpoint extrusion of the polymer in a solvent-gel phase via a syringe pump through a high voltage static field until it coalesces on a collector plate. A high-voltage power supply is connected to both the tip of the needle and to the collector plate, which creates the electrostatic field. A polymer stream within this field will be subjected to electrostatic forces, causing it to spin and elongate until it reaches the collector. This process also causes the solvent to evaporate, leaving on the collector plate a polymer mat with unique interstitial properties, and an excellent scaffold material for NMFs.This proposed project involves the fabrication and assembly of pilot electrospinning equipment at Sheridan College and construction of shielding for its safe operation. With the equipment in place, various polymers will be electrospun and their mechanical properties tested and compared to incumbent scaffolds used by industry partner Cnem Corporation. The company aims to produce NMF prototypes using the project's most successfully-spun polymer scaffolds.
Program
Applied Research and Development Grants - Level 1
Location
Ontario, Canada
Recipient Type
Academia
Type
Grant
Source
NSERC's Awards Data
As published
Application id
516411-2017
Name nom
England, Andrea
Department département
Head Office
Organization id
22156
Institution établissement
Sheridan Institute of Technology and Advanced Learning
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2017
Competition year année de concours
2017
Award amount
25000
Program id
CARD1
Program name en
Applied Research and Development Grants - Level 1
Program name fr
Subventions de recherche et développement appliquée - niveau 1
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
1561
Committee name en
Applied Research and Development Grants
Committee name fr
Subventions de recherche et développement appliquée
Area of application code
500
Area of application group en
Manufacturing processes and products
Area of application group fr
Procédés et produits industriels
Area of application en
Manufacturing processes and products
Area of application fr
Procédés et produits industriels
Research subject code
3750
Research subject group en
Polymer chemistry
Research subject group fr
Chimie des polymères
Research subject en
Polymer chemistry
Research subject fr
Chimie des polymères
Partie
1
Nb partie
1
Application title
Polymeric Nanofibres as a Scaffold for Nanoporous Metal Foams (NMFs) Production
Keyword
NSERC
Application summary
Currently, the compact and large surface-area properties of nanoporous metal foams (NMFs) allow for its use in various applications such as electrodes, sensors, and filters. With the market demanding electronic devices to continue to decrease in size while increasing in performance, the ultra-compact batteries powering them will see electrodes made of NMFs as an essential component. To manufacture NMFs, a polymer scaffold, such as a sponge, is often used as the starting material. There are applications that require maximum surface area, with target pore sizes of the scaffold to be between 5 and 20µm so that the final metallic void can reach a diameter ranging from less than 3nm to 1µm. Polymer foam scaffold manufactured through conventional production methods cannot create such fine pores. A promising technology called electrospinning has the ability to produce uniform nanoporous polymer structures for the subsequent production of NMFs. Electrospinning involves the pinpoint extrusion of the polymer in a solvent-gel phase via a syringe pump through a high voltage static field until it coalesces on a collector plate. A high-voltage power supply is connected to both the tip of the needle and to the collector plate, which creates the electrostatic field. A polymer stream within this field will be subjected to electrostatic forces, causing it to spin and elongate until it reaches the collector. This process also causes the solvent to evaporate, leaving on the collector plate a polymer mat with unique interstitial properties, and an excellent scaffold material for NMFs.This proposed project involves the fabrication and assembly of pilot electrospinning equipment at Sheridan College and construction of shielding for its safe operation. With the equipment in place, various polymers will be electrospun and their mechanical properties tested and compared to incumbent scaffolds used by industry partner Cnem Corporation. The company aims to produce NMF prototypes using the project's most successfully-spun polymer scaffolds.