Grant: Alliance Grants
Memorial University of Newfoundland
$254,000.00
Characterization and solvent extraction of rare earth elements
FY 2023-24
Summary
Rare earth elements (REEs), including scandium, yttrium, and fifteen lanthanides, are becoming increasingly important in the transition to a low-carbon, green economy due to their primary usage in permanent magnets, optics and lasers, catalysts, wind- and solar-energy conversion, and rechargeable batteries. Canada, despite being home to the most substantial reserves of REEs, has only recently commenced operations at its inaugural REE facility in Saskatchewan. The main barriers to the widespread hydrometallurgical processing of REEs are laborious procedures, economic and environmental concerns, and difficulties in identifying and separating REEs due to their physical and chemical similarity. To tackle these challenges, the proposed research aims to develop a two-level characterization strategy that combines the rapid X-ray fluorescence (XRF) method and the more accurate inductively coupled plasma mass spectroscopy (ICP-MS) for the determination of REEs based on their content levels in different feedstocks. Additionally, a generic methodology will be explored to assess the effectiveness of the extractant in the solvent-extraction separation of REEs from leachate solutions, utilizing density functional theory calculation, spectroscopic characterization, and experimental verification. Simulation and optimization methods will also be employed to reduce operating costs in the REE leaching and separation processes. Finally, cost-effective and environmentally friendly treatment technologies will be developed for liquid and solid wastes generated from REE processing to achieve nearly zero discharge of saline wastewater. By working closely with our industrial partner, the proposed research aims to generate valuable methodologies and insights, hence serving as a guiding framework for the development of the industrial-scale REE processing plant. Meanwhile, a unique environment will be created for the training of highly qualified personnel (HQP) in both fundamental and applied research.
Program
Alliance Grants
Recipient
Location
Newfoundland and Labrador, Canada
Recipient Type
Academia
Type
Grant
Source
NSERC's Awards Data
As published
Application id
586641-2023
Name nom
Zhang, Yan Y
Department département
Process Engineering
Organization id
89
Institution établissement
Memorial University of Newfoundland
Province en
Newfoundland and Labrador
Province fr
Terre-Neuve-et-Labrador
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2023
Competition year année de concours
2023
Award amount
254000
Program id
ALLRP
Program name en
Alliance Grants
Program name fr
Subventions Alliance
Group en
RESEARCH PARTNERSHIPS
Group fr
PARTENARIATS DE RECHERCHE
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
202
Area of application group en
Natural resources (economic aspects)
Area of application group fr
Ressources naturelles (aspects économiques)
Area of application en
Mineral resources ( prospecting, exploration, mining, extraction, processing)
Area of application fr
Ressources minérales (prospection, exploration, mines, extraction et préparation)
Research subject code
1806
Research subject group en
Chemical engineering
Research subject group fr
Separation processes
Research subject en
Génie chimique
Research subject fr
Procédés de séparation
Application title
Characterization and solvent extraction of rare earth elements
Keyword
Acidic and basic extractants; Coordination effects; Determination of rare earth elements; ICP-MS; Limit of detection; Reactive extraction; Solvent (liquid-liquid) extraction; Spectral interference; X-ray fluorescence spectroscopy
Application summary
Rare earth elements (REEs), including scandium, yttrium, and fifteen lanthanides, are becoming increasingly important in the transition to a low-carbon, green economy due to their primary usage in permanent magnets, optics and lasers, catalysts, wind- and solar-energy conversion, and rechargeable batteries. Canada, despite being home to the most substantial reserves of REEs, has only recently commenced operations at its inaugural REE facility in Saskatchewan. The main barriers to the widespread hydrometallurgical processing of REEs are laborious procedures, economic and environmental concerns, and difficulties in identifying and separating REEs due to their physical and chemical similarity. To tackle these challenges, the proposed research aims to develop a two-level characterization strategy that combines the rapid X-ray fluorescence (XRF) method and the more accurate inductively coupled plasma mass spectroscopy (ICP-MS) for the determination of REEs based on their content levels in different feedstocks. Additionally, a generic methodology will be explored to assess the effectiveness of the extractant in the solvent-extraction separation of REEs from leachate solutions, utilizing density functional theory calculation, spectroscopic characterization, and experimental verification. Simulation and optimization methods will also be employed to reduce operating costs in the REE leaching and separation processes. Finally, cost-effective and environmentally friendly treatment technologies will be developed for liquid and solid wastes generated from REE processing to achieve nearly zero discharge of saline wastewater. By working closely with our industrial partner, the proposed research aims to generate valuable methodologies and insights, hence serving as a guiding framework for the development of the industrial-scale REE processing plant. Meanwhile, a unique environment will be created for the training of highly qualified personnel (HQP) in both fundamental and applied research.