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Grant: Collaborative Research and Development Grants

Queen's University

$109,400.00

Block-random copolymers as stabilizers in emulsion polymerization_x000d_

FY 2020-21

Summary
Water-based coatings, sealants, paints and adhesives are environmentally friendly alternatives to solvent-based products, with lower toxicity, fewer harmful emissions to the environment and reduced risk to humans by exposure to harmful vapors. Despite their significant advantages compared to solvent-based products, water-based latexes are not without their concerns. One of the issues is the tendency for the "surfactant" or "stabilizer" (an essential component of the product that plays a critical role in ensuring the latexes exist as discrete particles suspended in water) to migrate out of the latex. The surfactant can end up in the environment if for example the product is an exterior paint, or it could result in human exposure if the product is for example an adhesive on produce labels. BASF, a global company with significant manufacturing operations in Canada is collaborating with Queen's University to develop a new type of stabilizer with the objective of overcoming deficiencies of existing stabilizer materials. The key to this research is the design of specially designed molecules that are much larger than traditional surfactants or soaps; one end of the molecule will strongly adhere to the particles, thereby preventing their migration to the environment. At the same time, the other end of the molecule or polymer chain, will have to fulfill a demanding set of properties to ensure the product can be manufactured safely and economically. Queen's and BASF researchers have designed a novel structure that meets these requirements, and will now seek to better understand their fundamental behaviour and properties. Our research will help Canadian industry address challenges in new product innovation, develop new innovative products with reduced environmental impact, and provide them with highly trained scientists with the skills required to remain internationally competitive.
Program
Collaborative Research and Development Grants
Location
Ontario, Canada
Recipient Type
Academia
Type
Grant
Source
NSERC's Awards Data

As published

Application id
531855-2018
Name nom
Cunningham, Michael
Department département
Chemical Engineering
Organization id
29
Institution établissement
Queen's University
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2020
Competition year année de concours
2018
Award amount
109400
Program id
CRDPJ
Program name en
Collaborative Research and Development Grants
Program name fr
Subventions de recherche et développement coopérative
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
602
Area of application group en
Construction, urban and rural planning
Area of application group fr
Construction, urbanisme et aménagement rural
Area of application en
Materials performance
Area of application fr
Performance des matériaux
Research subject code
3750
Research subject group en
Polymer chemistry
Research subject group fr
Chimie des polymères
Research subject en
Polymer chemistry
Research subject fr
Chimie des polymères
Installment
inst:2 - 2
Partie
1
Nb partie
2
Application title
Block-random copolymers as stabilizers in emulsion polymerization_x000d_
Keyword
NSERC
Application summary
Water-based coatings, sealants, paints and adhesives are environmentally friendly alternatives to solvent-based products, with lower toxicity, fewer harmful emissions to the environment and reduced risk to humans by exposure to harmful vapors. Despite their significant advantages compared to solvent-based products, water-based latexes are not without their concerns. One of the issues is the tendency for the "surfactant" or "stabilizer" (an essential component of the product that plays a critical role in ensuring the latexes exist as discrete particles suspended in water) to migrate out of the latex. The surfactant can end up in the environment if for example the product is an exterior paint, or it could result in human exposure if the product is for example an adhesive on produce labels. BASF, a global company with significant manufacturing operations in Canada is collaborating with Queen's University to develop a new type of stabilizer with the objective of overcoming deficiencies of existing stabilizer materials. The key to this research is the design of specially designed molecules that are much larger than traditional surfactants or soaps; one end of the molecule will strongly adhere to the particles, thereby preventing their migration to the environment. At the same time, the other end of the molecule or polymer chain, will have to fulfill a demanding set of properties to ensure the product can be manufactured safely and economically. Queen's and BASF researchers have designed a novel structure that meets these requirements, and will now seek to better understand their fundamental behaviour and properties. Our research will help Canadian industry address challenges in new product innovation, develop new innovative products with reduced environmental impact, and provide them with highly trained scientists with the skills required to remain internationally competitive.