Grant: Discovery Grants Program - Individual
University of Prince Edward Island
$20,000.00
Design of Redox-active Metal-Containing Macrocycles and Dendrimers
EF 2016-17
Résumé
The goal of this research is to design new synthetic approaches to making macromolecules that incorporate metallic moieties in their structures. The presence of the metal will facilitate the gain/loss of electrons. The proposed materials will also have properties that are useful in the design of new materials, which foster developments in science and technology. For instance, the polymers capable of detecting carbon monoxide in the environment, encapsulating environmental pollutants such as lead(II), cadmium(II), mercury(II), and phenols, will be designed. We will also design a new synthetic route to polymers that harvest solar energy and use the energy to initiate the flow of electrons as an in electrical conductor. Some of the proposed polymers will have magnetic properties and bioactive properties, as well as high thermal stability. Although, many of these polymers are known and are obtained via laborious synthetic methods, we propose to synthesize these polymers via an innovative, a cost effective and simple method. Our success will greatly reduce the cost of these polymers. Most of these reactions will use iron-containing materials as a mediator since the reaction conditions are mild and the relatively low cost associated with the iron starting materials.
Our research laboratory is equipped with the necessary instruments to synthesize and characterize the newly prepared monomers and macromolecules. Both undergraduate and graduate students involved in this research program will acquire the necessary skills that will contribute to the advancement of their future careers in industry or academia.
Programme
Discovery Grants Program - Individual
Bénéficiaire
Emplacement
Prince Edward Island, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data
Tel que publié
Application id
RGPIN-2015-04219
Name nom
AbdElAziz, Alaa
Department département
Chemistry - Chemistry
Organization id
88
Institution établissement
University of Prince Edward Island
Province en
Prince Edward Island
Province fr
?le-du-Prince-Édouard
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2016
Competition year année de concours
2015
Award amount
20000
Program id
RGPIN
Program name en
Discovery Grants Program - Individual
Program name fr
Programme de subventions à la découverte - individuelles
Group en
Discovery grants programs
Group fr
Programmes de subventions à la découverte
Committee code
1504
Committee name en
Chemistry
Committee name fr
Chimie
Area of application code
1208
Area of application group en
Advancement of knowledge
Area of application group fr
Avancement des connaissances
Area of application en
Materials sciences
Area of application fr
Sciences des matériaux
Research subject code
3751
Research subject group en
Polymer chemistry
Research subject group fr
Chimie des polymères
Research subject en
Polymer synthesis
Research subject fr
Synthèse des polymères
Partie
1
Nb partie
1
Application title
Design of Redox-active Metal-Containing Macrocycles and Dendrimers
Keyword
NSERC
Application summary
The goal of this research is to design new synthetic approaches to making macromolecules that incorporate metallic moieties in their structures. The presence of the metal will facilitate the gain/loss of electrons. The proposed materials will also have properties that are useful in the design of new materials, which foster developments in science and technology. For instance, the polymers capable of detecting carbon monoxide in the environment, encapsulating environmental pollutants such as lead(II), cadmium(II), mercury(II), and phenols, will be designed. We will also design a new synthetic route to polymers that harvest solar energy and use the energy to initiate the flow of electrons as an in electrical conductor. Some of the proposed polymers will have magnetic properties and bioactive properties, as well as high thermal stability. Although, many of these polymers are known and are obtained via laborious synthetic methods, we propose to synthesize these polymers via an innovative, a cost effective and simple method. Our success will greatly reduce the cost of these polymers. Most of these reactions will use iron-containing materials as a mediator since the reaction conditions are mild and the relatively low cost associated with the iron starting materials.
Our research laboratory is equipped with the necessary instruments to synthesize and characterize the newly prepared monomers and macromolecules. Both undergraduate and graduate students involved in this research program will acquire the necessary skills that will contribute to the advancement of their future careers in industry or academia.