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Grant: Alliance Grants

Université d'Ottawa

$50,000.00

Semi batch synthesis of poly(ionic liquid) block copolymers for use in electrochromic applications

EF 2024-25

Résumé
The partnership between the university of Ottawa and Trusscore Inc. is to increase the potential of electrochromic devices through the development polymer electrolytes that are safer, easier to manufacture and lead to less device failure. As a bias is applied, conduction through the electrolyte activates the electrochromic material, creating a change in colour. Electrochromic devices currently use solution-based electrolytes which are problematic as they often lead to product failure due to loss of stability and are often toxic which is problematic if a leak occurs. Building on our recent successes we propose to synthesize and optimize poly(ionic liquid) based block copolymers by semi-batch nitroxide mediated polymerization to act as safer, and higher performing polymer electrolytes. Nitroxide mediated polymerization is an industrially relevant synthetic technique and through a semi-batch approach we will target reduction in the synthetic complexity and increase the potential for commercialization. Through iterative design and constant feedback from the Trusscore team on the manufacturability, integration and device performance we will continuously improve the design of our polymers to ensure the required criteria are met or surpassed.
Programme
Alliance Grants
Bénéficiaire
Emplacement
Ontario, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data

Tel que publié

Application id
580906-2022
Name nom
Lessard, Benoit BH
Department département
Chemical and Biological Engineering
Organization id
28
Institution établissement
Université d'Ottawa
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2024
Competition year année de concours
2022
Award amount
50000
Program id
ALLRP
Program name en
Alliance Grants
Program name fr
Subventions Alliance
Group en
RESEARCH PARTNERSHIPS
Group fr
PARTENARIATS DE RECHERCHE
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
513
Area of application group en
Manufacturing processes and products
Area of application group fr
Procédés et produits industriels
Area of application en
Electrical and electronic machinery and equipment (including computer hardware)
Area of application fr
Machinerie et équipement électriques et électroniques (y compris matériel informatique)
Research subject code
2004
Research subject group en
Materials science and technology
Research subject group fr
Science et technologie des matériaux
Research subject en
Polymers and coatings
Research subject fr
Polymères et revêtements
Field of research list names en
Not available
Field of research list names fr
Non disponible
Socioeconomic objective list names en
Not available
Socioeconomic objective list names fr
Non disponible
Application title
Semi batch synthesis of poly(ionic liquid) block copolymers for use in electrochromic applications
Keywords
block copolymers; controlled radical polymerization; electrochemistry; electrochromic devices; material characterization; polymer electrolytes; polymer engineering; polymer reaction engineering; thin film organic electronics; thin film processing
Application summary
The partnership between the university of Ottawa and Trusscore Inc. is to increase the potential of electrochromic devices through the development polymer electrolytes that are safer, easier to manufacture and lead to less device failure. As a bias is applied, conduction through the electrolyte activates the electrochromic material, creating a change in colour. Electrochromic devices currently use solution-based electrolytes which are problematic as they often lead to product failure due to loss of stability and are often toxic which is problematic if a leak occurs. Building on our recent successes we propose to synthesize and optimize poly(ionic liquid) based block copolymers by semi-batch nitroxide mediated polymerization to act as safer, and higher performing polymer electrolytes. Nitroxide mediated polymerization is an industrially relevant synthetic technique and through a semi-batch approach we will target reduction in the synthetic complexity and increase the potential for commercialization. Through iterative design and constant feedback from the Trusscore team on the manufacturability, integration and device performance we will continuously improve the design of our polymers to ensure the required criteria are met or surpassed.