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Grant: Discovery Grants Program - Individual

Université du Québec à Chicoutimi

$46,000.00

Improvement of carbon anode quality in view of reducing energy consumption and environmental emissions in aluminum industry

EF 2024-25

Résumé
The global objective is to improve anodes by developing new technologies, which are not yet used in industry, in view of reducing energy consumption and greenhouse gas (GHG) emissions. They are original and fundamental in nature. Project 1- Utilization of graphene in anode production: The energy consumption is a major part of the aluminum production cost. Improving anode quality decreases the cost, energy, carbon consumption, and GHG emissions. Graphene conducts electricity efficiently. It has been the subject of many innovations, but it was never used in anodes. Replacing a small part of coke with graphene could decrease the anode electrical resistivity, hence energy consumption. The study also aims to produce graphene from rejected anodes instead of graphite to add value to industrial rejects. This has never been done before. Project 2- Rheological behavior of anode paste: A new tool will be developed to understand the rheological behavior of anode paste and correlate this with anode properties. This will make the assessment of anode quality possible from the paste quality before anode production. It will also permit the determination of the optimum pitch quantity, which is currently adjusted by trial and error in plants. Project 3- Utilization of high softening-point pitch (HSPP) in anode making: The low softening-point pitches release volatiles containing PAHs during anode baking and increase the GHG emissions. HSPPs have lower volatile content, which would decrease the GHG emissions. However, the volatiles provide half of the energy needed for anode baking. A decrease in volatiles will increase the fuel requirement. The objective is to determine the impact of using HSPP on anode quality, cost, and GHG emissions. Project 4- Anode assembly without using cast iron: Anodes are paired with an anode assembly and installed in an electrolysis cell. The anode assembly consists of steel stubs that fit into anode holes, a crossbar that connects the stubs, and a rod that is attached to the crossbar. Hot cast iron at is poured into the space between the stubs and the anode carbon to hold them together. The electrical resistances of cell components affect energy consumption. In this project, a new anode assembly will be developed, which will eliminate the utilization of cast iron and hence anode/cast iron and cast iron/steel interface resistances, reducing the energy consumption. Also, the amount of anode butts produced will be reduced since a larger portion of the anodes can be used for the electrolysis.
Programme
Discovery Grants Program - Individual
Emplacement
Quebec, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data

Tel que publié

Application id
RGPIN-2019-05331
Name nom
Kocaefe, Duygu
Department département
Sciences appliquées - Sciences appliquées
Organization id
52
Institution établissement
Université du Québec à Chicoutimi
Province en
Québec
Province fr
Québec
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2024
Competition year année de concours
2019
Award amount
46000
Program id
RGPIN
Program name en
Discovery Grants Program - Individual
Program name fr
Programme de subventions à la découverte - individuelles
Group en
DISCOVERY RESEARCH
Group fr
RECHERCHE AXÉE SUR LA DÉCOUVERTE
Committee code
1511
Committee name en
Materials and Chemical Engineering
Committee name fr
Génie chimique et des matériaux
Area of application code
400
Area of application group en
Environment
Area of application group fr
Environnement
Area of application en
Environment
Area of application fr
Environnement
Research subject code
1801
Research subject group en
Chemical engineering
Research subject group fr
Génie chimique
Research subject en
Reaction fundamentals and reactor design
Research subject fr
Principes des réactions et conception de réacteurs
Field of research list names en
Not available
Field of research list names fr
Non disponible
Socioeconomic objective list names en
Not available
Socioeconomic objective list names fr
Non disponible
Application title
Improvement of carbon anode quality in view of reducing energy consumption and environmental emissions in aluminum industry
Keywords
carbone anodes for aluminum production; graphene utilization in anodes; energy consumption; ges emission; anode paste rheology; high softening point pitch; volatile release kinetics; characterization; anode assembly; anode properties
Application summary
The global objective is to improve anodes by developing new technologies, which are not yet used in industry, in view of reducing energy consumption and greenhouse gas (GHG) emissions. They are original and fundamental in nature. Project 1- Utilization of graphene in anode production: The energy consumption is a major part of the aluminum production cost. Improving anode quality decreases the cost, energy, carbon consumption, and GHG emissions. Graphene conducts electricity efficiently. It has been the subject of many innovations, but it was never used in anodes. Replacing a small part of coke with graphene could decrease the anode electrical resistivity, hence energy consumption. The study also aims to produce graphene from rejected anodes instead of graphite to add value to industrial rejects. This has never been done before. Project 2- Rheological behavior of anode paste: A new tool will be developed to understand the rheological behavior of anode paste and correlate this with anode properties. This will make the assessment of anode quality possible from the paste quality before anode production. It will also permit the determination of the optimum pitch quantity, which is currently adjusted by trial and error in plants. Project 3- Utilization of high softening-point pitch (HSPP) in anode making: The low softening-point pitches release volatiles containing PAHs during anode baking and increase the GHG emissions. HSPPs have lower volatile content, which would decrease the GHG emissions. However, the volatiles provide half of the energy needed for anode baking. A decrease in volatiles will increase the fuel requirement. The objective is to determine the impact of using HSPP on anode quality, cost, and GHG emissions. Project 4- Anode assembly without using cast iron: Anodes are paired with an anode assembly and installed in an electrolysis cell. The anode assembly consists of steel stubs that fit into anode holes, a crossbar that connects the stubs, and a rod that is attached to the crossbar. Hot cast iron at is poured into the space between the stubs and the anode carbon to hold them together. The electrical resistances of cell components affect energy consumption. In this project, a new anode assembly will be developed, which will eliminate the utilization of cast iron and hence anode/cast iron and cast iron/steel interface resistances, reducing the energy consumption. Also, the amount of anode butts produced will be reduced since a larger portion of the anodes can be used for the electrolysis.