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Grant: Canada Research Chairs

York University

$100,000.00

Main-Group Catalysis and Sustainable Chemistry

EF 2024-25

Résumé
Chemicals make up the core building blocks for all products that our society relies on (for example, pharmaceuticals for health, agrochemicals for food, advanced materials for microchips, dyes for cosmetics, just to name a few). Unfortunately, the production of chemicals is an energy intensive and polluting process, consuming ~10% of global oil and gas supplies and accounting for ~15% of global emissions. The challenges we face demand a significantly more sustainable approach towards creating these building blocks, and chemists are uniquely positioned to provide solutions. Dr. Caputo’s research program will tackle this problem through a two-pronged approach. The first is developing greener catalysts to create these desired materials – a catalyst is a molecule that lowers the barriers to a chemical reaction, allowing them to proceed using less energy. Unfortunately, many industrial catalysts are based off precious metals, which are rare, expensive, and unsustainable. Dr. Caputo’s research will develop alternatives using earth abundant main-group elements. Recent discoveries have found these metal-free alternatives are nearly as effective as their precious metal counterparts for several key reactions, including the hydrogenation of unsaturated substrates. His research also seeks to understand the fundamental reasons what makes these main-group catalysts effective and use this data to create superior systems. The second approach looks to develop value added molecules from renewable feedstocks, as opposed to the ubiquitously used petroleum feedstocks. This program will apply synthetic chemistry approaches towards specific natural products to develop a first of its kind long lasting personal products, initially targeting ultra long-lasting sun protection. These have the potential to revolutionize the personal care space and would undoubtedly result in significant IP protection and commercialization.
Programme
Canada Research Chairs
Bénéficiaire
Emplacement
Ontario, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data

Tel que publié

Application id
CRC-2021-00020
Name nom
Caputo, Christopher
Department département
Chemistry - York University
Organization id
38
Institution établissement
York University
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2024
Competition year année de concours
2021
Award amount
100000
Program id
CRC
Program name en
Canada Research Chairs
Program name fr
Chaires de recherche du Canada
Group en
DISCOVERY RESEARCH
Group fr
RECHERCHE AXÉE SUR LA DÉCOUVERTE
Committee code
9998
Committee name en
Canada Research Chair Selection Committee
Committee name fr
Comité de sélection des Chaires de recherche du Canada
Area of application code
9999
Area of application group en
Not available
Area of application group fr
Non disponible
Area of application en
Not available
Area of application fr
Non disponible
Research subject code
9999
Research subject group en
Not available
Research subject group fr
Non disponible
Research subject en
Not available
Research subject fr
Non disponible
Field of research list codes
RDF1040204
Field of research list names en
Main group metal chemistry
Field of research list names fr
Chimie des métaux du groupe principal
Socioeconomic objective list codes
RDS10201
Socioeconomic objective list names en
Environmentally sustainable human activities
Socioeconomic objective list names fr
Activités humaines écologiquement durables
Application title
Main-Group Catalysis and Sustainable Chemistry
Keywords
Lewis Acids; Non-Innocent Ligands; Renewable Feedstocks; Sunscreens; Main Group Chemistry; Catalysis; Inorganic Chemistry; Organic Chemistry
Application summary
Chemicals make up the core building blocks for all products that our society relies on (for example, pharmaceuticals for health, agrochemicals for food, advanced materials for microchips, dyes for cosmetics, just to name a few). Unfortunately, the production of chemicals is an energy intensive and polluting process, consuming ~10% of global oil and gas supplies and accounting for ~15% of global emissions. The challenges we face demand a significantly more sustainable approach towards creating these building blocks, and chemists are uniquely positioned to provide solutions. Dr. Caputo’s research program will tackle this problem through a two-pronged approach. The first is developing greener catalysts to create these desired materials – a catalyst is a molecule that lowers the barriers to a chemical reaction, allowing them to proceed using less energy. Unfortunately, many industrial catalysts are based off precious metals, which are rare, expensive, and unsustainable. Dr. Caputo’s research will develop alternatives using earth abundant main-group elements. Recent discoveries have found these metal-free alternatives are nearly as effective as their precious metal counterparts for several key reactions, including the hydrogenation of unsaturated substrates. His research also seeks to understand the fundamental reasons what makes these main-group catalysts effective and use this data to create superior systems. The second approach looks to develop value added molecules from renewable feedstocks, as opposed to the ubiquitously used petroleum feedstocks. This program will apply synthetic chemistry approaches towards specific natural products to develop a first of its kind long lasting personal products, initially targeting ultra long-lasting sun protection. These have the potential to revolutionize the personal care space and would undoubtedly result in significant IP protection and commercialization.