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Grant: Engage Grants Program

Saint Mary's University

$25,000.00

Evaluation of new phosphonium ionic liquids as additives for lubricants

EF 2011-12

Résumé
Energy efficient processes are central to the development of a green economy. A key component of energy efficiency is the use of lubricants as these generally reduce friction, wear and corrosion of moving mechanical parts. Mineral and synthetic oil lubricants have been used successfully for many years, however, many mineral oils oxidize rapidly at temperatures above 100°C. This is a serious drawback to their effective application resulting in insufficient lubricity and unacceptably short drain intervals. The development of synthetic oils, including groups such as silicones, poly-alpha olefins, polyalkylene glycols, polyol esters, and fluorinated derivatives, circumvented these problems. Additives are also often added to the bulk synthetic oil to improve performance. These include antioxidants (phenolic compounds, aromatic amines, sulfur containing compounds, or inorganic zinc and copper containing materials) and extreme pressure and antiwear agents. Oils must be highly stable and chemically inert under increasingly harsh friction conditions, and traditional additives are now often found to be inadequate. Ionic liquids on the other hand, are ideal candidates for synthetic oil additives. They offer a new approach for the high performance lubricant market due to their unique combination of material properties including: negligible volatility, low flammability, high thermal stability, low melting point, broad liquid range and controlled miscibility with organic compounds. We are keenly interested in exploring the potential of ionic liquids as new lubricants via the proposed project. We will prepare and characterize new ionic liquids for this purpose and assess the suitability of ILs as additives for lubrication oils. Due to the confidential nature of the work, details on the market, partner, and specific project are revealed ONLY in the confidential portion of the proposal.
Programme
Engage Grants Program
Emplacement
Nova Scotia, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data

Tel que publié

Application id
425935-2011
Name nom
Clyburne, Jason
Department département
Chemistry
Organization id
85
Institution établissement
Saint Mary's University
Province en
Nova Scotia
Province fr
Nouvelle-Écosse
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2011
Competition year année de concours
2011
Award amount
25000
Program id
EGP
Program nane en
Engage Grants Program
Program name fr
Programme de subventions d'engagement partenariat
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
1551
Committee name en
Atlantic Internal Decision Committee
Committee name fr
Comité de décision interne pour l'Atlantique
Area of application code
507
Area of application group en
Manufacturing processes and products
Area of application group fr
Procédés et produits industriels
Area of application en
Industrial chemicals (solvents, resins)
Area of application fr
Produits chimiques industriels (solvants, résines)
Research subject code
2000
Research subject group en
Materials science and technology
Research subject group fr
Science et technologie des matériaux
Research subject en
Materials science and technology
Research subject fr
Science et technologie des matériaux
Partie
1
Nb partie
1
Application title
Evaluation of new phosphonium ionic liquids as additives for lubricants
Keyword
NSERC
Application summary
Energy efficient processes are central to the development of a green economy. A key component of energy efficiency is the use of lubricants as these generally reduce friction, wear and corrosion of moving mechanical parts. Mineral and synthetic oil lubricants have been used successfully for many years, however, many mineral oils oxidize rapidly at temperatures above 100°C. This is a serious drawback to their effective application resulting in insufficient lubricity and unacceptably short drain intervals. The development of synthetic oils, including groups such as silicones, poly-alpha olefins, polyalkylene glycols, polyol esters, and fluorinated derivatives, circumvented these problems. Additives are also often added to the bulk synthetic oil to improve performance. These include antioxidants (phenolic compounds, aromatic amines, sulfur containing compounds, or inorganic zinc and copper containing materials) and extreme pressure and antiwear agents. Oils must be highly stable and chemically inert under increasingly harsh friction conditions, and traditional additives are now often found to be inadequate. Ionic liquids on the other hand, are ideal candidates for synthetic oil additives. They offer a new approach for the high performance lubricant market due to their unique combination of material properties including: negligible volatility, low flammability, high thermal stability, low melting point, broad liquid range and controlled miscibility with organic compounds. We are keenly interested in exploring the potential of ionic liquids as new lubricants via the proposed project. We will prepare and characterize new ionic liquids for this purpose and assess the suitability of ILs as additives for lubrication oils. Due to the confidential nature of the work, details on the market, partner, and specific project are revealed ONLY in the confidential portion of the proposal.