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Grant: Alliance Grants

University of Alberta

$189,733.00

Synthetic jet fuel: Durene solubility and transalkylation

EF 2024-25

Résumé
Synthetic fuel is a collective term used for transport fuel that is produced from resources other than petroleum. One potential pathway for the production of synthetic jet fuel and diesel fuel is to make use of methanol as a starting material and is converted though the methanol-to-hydrocarbon synthesis process. When methanol-to-hydrocarbon synthesis is employed to produce fully formulated synthetic kerosene for jet fuel a disproportionately large amount of durene (1,2,4,5-tetramethylbenzene) is found in the product. Due to durene's high freezing point (around +80 C), it affects the formulation of jet fuel, as well as Canadian winter diesel fuel. The purpose of the project is twofold. Its first objective is to generate solubility data for engineering design that is also necessary to determine the blending threshold of durene in jet fuel and diesel fuel. Its second objective is to determine the performance of transalkylation to convert durene with lighter aromatics to meet fuel property requirements without an accompanying yield loss. Transalkylation is an industrially practiced process, but it has not been applied for durene conversion, which is why it is necessary to evaluate its performance for durene conversion. On successful completion the project will facilitate the design of a practical process that can produce fully formulated kerosene for jet fuel and Canadian winter diesel fuel from methanol.
Programme
Alliance Grants
Bénéficiaire
Emplacement
Alberta, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data

Tel que publié

Application id
591006-2023
Name nom
De Klerk, Arno A
Department département
Chemical and Materials Engineering
Organization id
9
Institution établissement
University of Alberta
Province en
Alberta
Province fr
Alberta
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2024
Competition year année de concours
2023
Award amount
189733
Program id
ALLRP
Program name en
Alliance Grants
Program name fr
Subventions Alliance
Group en
RESEARCH PARTNERSHIPS
Group fr
PARTENARIATS DE RECHERCHE
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
303
Area of application group en
Energy resources
Area of application group fr
Ressources d'énergie
Area of application en
Alternative energy resources
Area of application fr
Autres ressources d'énergie
Research subject code
1800
Research subject group en
Chemical engineering
Research subject group fr
Génie chimique
Research subject en
Chemical engineering
Research subject fr
Génie chimique
Field of research list names en
Not available
Field of research list names fr
Non disponible
Socioeconomic objective list names en
Not available
Socioeconomic objective list names fr
Non disponible
Application title
Synthetic jet fuel: Durene solubility and transalkylation
Keywords
acid catalysis; cold flow properties; differential scanning calorimetry; methanol-to-jet; solubility; synthetic diesel fuel; synthetic jet fuel; transalkylation
Application summary
Synthetic fuel is a collective term used for transport fuel that is produced from resources other than petroleum. One potential pathway for the production of synthetic jet fuel and diesel fuel is to make use of methanol as a starting material and is converted though the methanol-to-hydrocarbon synthesis process. When methanol-to-hydrocarbon synthesis is employed to produce fully formulated synthetic kerosene for jet fuel a disproportionately large amount of durene (1,2,4,5-tetramethylbenzene) is found in the product. Due to durene's high freezing point (around +80 C), it affects the formulation of jet fuel, as well as Canadian winter diesel fuel. The purpose of the project is twofold. Its first objective is to generate solubility data for engineering design that is also necessary to determine the blending threshold of durene in jet fuel and diesel fuel. Its second objective is to determine the performance of transalkylation to convert durene with lighter aromatics to meet fuel property requirements without an accompanying yield loss. Transalkylation is an industrially practiced process, but it has not been applied for durene conversion, which is why it is necessary to evaluate its performance for durene conversion. On successful completion the project will facilitate the design of a practical process that can produce fully formulated kerosene for jet fuel and Canadian winter diesel fuel from methanol.