Grant: Alliance Grants
University of New Brunswick
$100,700.00
Chemistry Control During Long-Term Storage of SMR Used Fuel
EF 2023-24
Résumé
Small modular reactors (SMRs) have been identified as having great potential to meet society's needs for carbon-free, safe, and cost-effective energy. The proposed, long-term disposal of Canada's current used nuclear fuel is in a deep geological repository (DGR), with waste forms from new nuclear technologies currently planned to be stored likewise. As DGR storage is expected to last centuries, scenarios such as water infiltration into storage containers, seeping through the outer defense barriers, require consideration. With a variety of proposed SMR fuel types, sizes, and compositions, some fuel waste forms may require further processing to meet the waste acceptance criteria for Canada's future DGR. This is particularly important for SMRs proposing to use sodium metal as a layer between the fuel and the fuel cladding to improve heat transfer, as sodium is highly reactive with water. Experiments on water ingress through storage canisters and fuel cladding have not yet been adapted to SMR spent fuels. In partnership with the CanmetMATERIALS laboratory in Hamilton, Ontario, a custom test cell, representative of the current defence in depth approach to DGR storage, will be designed and commissioned to conduct leak testing. Experiments will simulate groundwater ingress into the used fuel storage container along with some initial cladding damage. Changes to the local environment (pH, temperature, hydrogen gas evolution) due to the resulting water-sodium bond interactions will be monitored, including the subsequent degradation rate of the cladding and storage container materials. This program supports the pathway to commercialization of SMRs in Canada, ensuring that several knowledge gaps in the safe, long-term storage of SMR fuel in a DGR environment are addressed.
Programme
Alliance Grants
Bénéficiaire
Emplacement
New Brunswick, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data
Tel que publié
Application id
580467-2022
Name nom
Palazhchenko, Olga OY
Department département
Chemical Engineering
Organization id
75
Institution établissement
University of New Brunswick
Province en
New Brunswick
Province fr
Nouveau-Brunswick
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2023
Competition year année de concours
2022
Award amount
100700
Program id
ALLRP
Program name en
Alliance Grants
Program name fr
Subventions Alliance
Group en
RESEARCH PARTNERSHIPS
Group fr
PARTENARIATS DE RECHERCHE
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
302
Area of application group en
Energy resources
Area of application group fr
Ressources d'énergie
Area of application en
Nuclear energy
Area of application fr
Énergie nucléaire
Research subject code
1805
Research subject group en
Chemical engineering
Research subject group fr
Transport processes
Research subject en
Génie chimique
Research subject fr
Procédés de transfert
Application title
Chemistry Control During Long-Term Storage of SMR Used Fuel
Keyword
advanced nuclear; deep geological repository; flooding experiments; liquid metal corrosion; metallic fuel reactions; molten salt corrosion; radioactivity transport model; small modular reactor; sodium-fast reactor
Application summary
Small modular reactors (SMRs) have been identified as having great potential to meet society's needs for carbon-free, safe, and cost-effective energy. The proposed, long-term disposal of Canada's current used nuclear fuel is in a deep geological repository (DGR), with waste forms from new nuclear technologies currently planned to be stored likewise. As DGR storage is expected to last centuries, scenarios such as water infiltration into storage containers, seeping through the outer defense barriers, require consideration. With a variety of proposed SMR fuel types, sizes, and compositions, some fuel waste forms may require further processing to meet the waste acceptance criteria for Canada's future DGR. This is particularly important for SMRs proposing to use sodium metal as a layer between the fuel and the fuel cladding to improve heat transfer, as sodium is highly reactive with water. Experiments on water ingress through storage canisters and fuel cladding have not yet been adapted to SMR spent fuels. In partnership with the CanmetMATERIALS laboratory in Hamilton, Ontario, a custom test cell, representative of the current defence in depth approach to DGR storage, will be designed and commissioned to conduct leak testing. Experiments will simulate groundwater ingress into the used fuel storage container along with some initial cladding damage. Changes to the local environment (pH, temperature, hydrogen gas evolution) due to the resulting water-sodium bond interactions will be monitored, including the subsequent degradation rate of the cladding and storage container materials. This program supports the pathway to commercialization of SMRs in Canada, ensuring that several knowledge gaps in the safe, long-term storage of SMR fuel in a DGR environment are addressed.