Grant: Automotive Partnership Canada Project
École Polytechnique de Montréal
$245,770.00
Scale-up of a novel melt-synthesis process for the manufacturing of C-LiFePO4 for automotive applications
EF 2013-14
Résumé
Liquid phase synthesis of LiFeP04 has already been demonstrated in laboratory-scale trials and was identified as apossible low-cost alternative for manufacturing pathway. The high temperautre process in the liquid phase, benefitsfrom rapid reaction kinetics and the thermodynamic stability of LiFeP04 in a reducing atmosphere. The aim of thepresent proposed work is to develop and pilot of the molten synthesis process and accelerate its scale-up to acommercial-scale for the manufacturing of low-cost C-LiFeP04 for EV and PHEV applications.Main project steps are:1. Reactant selection and formulation2. Degassing, mixing, melting and casting3. Ingot comminution to'sub-micron size4. Spray drying (if needed, following wet milling)5. Pyrolysis and carbon coating (optionally in a gas-solid contactor)6. Laboratory testing in small cells7. Field testing by customers EV and PHEV applications8. Techno-economic evaluation of industrial-scale plantSteps 2 and 3 are seen as the most critical to achieve the project goals of cost and stable performance on cycling.Step 5 is also an important step. II is believed that carbon deposition in a gas-solid c6ntactor (e.g. fluidized bed) willimprove the performance (e.g. cycle-life, conductivity) of the C-LiFeP04 over Phostech's existing carbon coatingapproach.
Programme
Automotive Partnership Canada Project
Bénéficiaire
Emplacement
Quebec, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data
Tel que publié
Application id
435543-2012
Name nom
Patience, GregoryS
Department département
Génie chimique
Organization id
64
Institution établissement
École Polytechnique de Montréal
Province en
Québec
Province fr
Québec
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2013
Competition year année de concours
2012
Award amount
245770
Program id
APCPJ
Program name en
Automotive Partnership Canada Project
Program name fr
Partenariat automobile du Canada
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
141
Committee name en
University/Industry
Committee name fr
Universités/industrie
Area of application code
305
Area of application group en
Energy resources
Area of application group fr
Ressources d'énergie
Area of application en
Energy storage and conversion
Area of application fr
Stockage et transformation de l'énergie
Research subject code
3401
Research subject group en
Physical chemistry
Research subject group fr
Chimie physique
Research subject en
Electrochemistry
Research subject fr
Électrochimie
Partie
1
Nb partie
5
Application title
Scale-up of a novel melt-synthesis process for the manufacturing of C-LiFePO4 for automotive applications
Keyword
NSERC
Application summary
Liquid phase synthesis of LiFeP04 has already been demonstrated in laboratory-scale trials and was identified as apossible low-cost alternative for manufacturing pathway. The high temperautre process in the liquid phase, benefitsfrom rapid reaction kinetics and the thermodynamic stability of LiFeP04 in a reducing atmosphere. The aim of thepresent proposed work is to develop and pilot of the molten synthesis process and accelerate its scale-up to acommercial-scale for the manufacturing of low-cost C-LiFeP04 for EV and PHEV applications.Main project steps are:1. Reactant selection and formulation2. Degassing, mixing, melting and casting3. Ingot comminution to'sub-micron size4. Spray drying (if needed, following wet milling)5. Pyrolysis and carbon coating (optionally in a gas-solid contactor)6. Laboratory testing in small cells7. Field testing by customers EV and PHEV applications8. Techno-economic evaluation of industrial-scale plantSteps 2 and 3 are seen as the most critical to achieve the project goals of cost and stable performance on cycling.Step 5 is also an important step. II is believed that carbon deposition in a gas-solid c6ntactor (e.g. fluidized bed) willimprove the performance (e.g. cycle-life, conductivity) of the C-LiFeP04 over Phostech's existing carbon coatingapproach.