Grant: Discovery Grants Program - Individual
Royal Military College of Canada
$27,000.00
Investigations and Applications of Non-Conventional Energetic Materials
EF 2020-21
Résumé
The behaviour of heterogeneous high explosives (HHEs) at engineering scales is governed by the quantity and type of heterogeneous inclusions in the HE. Examples of HHEs include: explosives containing large fractions of dense, inert particles (steel or tungsten), or mixtures which react at the interface between fuel and oxidizer phases. HHEs are the primary type of explosive used in mining and civilian blasting, and are increasingly important in military ordnance. While the extreme conditions encountered in explosions are outside everyday experience, understanding phenomena associated with detonation and explosion of HHEs is critical to their safe, effective, and efficient use. The engineering output of explosives used in mining and civil engineering applications is indirectly felt by all citizens through consumption of material goods and use of public infrastructure. The proposed research program focuses on four sub topics that investigate the behaviour of HHEs at different scales of effect:
1) Impact initiation of HHEs: Impact by a high velocity projectile transmits a shock wave into the impacted material. If the material is energetic, chemical reaction will occur, possibly resulting in transition from fast burning to detonation. Explosive initiation by projectile impact is quantified by the shock pressure and volume of explosive material that is shocked with little curvature of the shock front. The presence of large fractions of heterogeneities modifies the sensitivity to shock, such that more of the shock front may produce detonation. Experimental ballistic impact tests are required to extend existing scaling laws to HHEs.
2) Detonation structure of HHEs: Ideal explosives detonate with a structure known as the Zel'dovichvon NeumannDöring (ZND) detonation: a strong inert shock that initiates chemical reaction, which progresses for a discrete amount of time and then stops. Solid explosive is converted into high temperature, high pressure gas that accelerates to sonic and then supersonic velocities soon after reaction completes. The large quantity and extreme mismatch of heterogeneities in HHEs can modify the detonation structure. Experimental measurements will be performed using time resolved free surface velocity measurement and impedance matching.
3) Modelling of particles in donation product flow: A critical factor governing the ability of HHEs to accelerate material is the energy transferred between the gaseous detonation products and solid particles in the flow. Multiphase simulations will be performed to elucidate this transfer.
4) Blast from HHEs: The presence of particles in the blast generated by an HHE historically complicated measurement of the impulse imparted at a distance from the charge. Novel laser velocimetry and spectroscopy techniques permit measurement of the complete impulse and enable correlation with exothermic reaction of the particles in air.
Programme
Discovery Grants Program - Individual
Bénéficiaire
Emplacement
Ontario, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data
Tel que publié
Application id
RGPIN-2018-06905
Name nom
Loiseau, Jason
Department département
Chemistry and Chemical Engineering
Organization id
30
Institution établissement
Royal Military College of Canada
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2020
Competition year année de concours
2018
Award amount
27000
Program id
RGPIN
Program name en
Discovery Grants Program - Individual
Program name fr
Programme de subventions à la découverte - individuelles
Group en
Discovery grants programs
Group fr
Programmes de subventions à la découverte
Committee code
1512
Committee name en
Mechanical Engineering
Committee name fr
Génie mécanique
Area of application code
1202
Area of application group en
Advancement of knowledge
Area of application group fr
Avancement des connaissances
Area of application en
Physical sciences
Area of application fr
Sciences physiques
Research subject code
2110
Research subject group en
Mechanical engineering
Research subject group fr
Génie mécanique
Research subject en
Combustion
Research subject fr
Combustion
Installment
inst:3-5
Partie
3
Nb partie
5
Application title
Investigations and Applications of Non-Conventional Energetic Materials
Keyword
NSERC
Application summary
The behaviour of heterogeneous high explosives (HHEs) at engineering scales is governed by the quantity and type of heterogeneous inclusions in the HE. Examples of HHEs include: explosives containing large fractions of dense, inert particles (steel or tungsten), or mixtures which react at the interface between fuel and oxidizer phases. HHEs are the primary type of explosive used in mining and civilian blasting, and are increasingly important in military ordnance. While the extreme conditions encountered in explosions are outside everyday experience, understanding phenomena associated with detonation and explosion of HHEs is critical to their safe, effective, and efficient use. The engineering output of explosives used in mining and civil engineering applications is indirectly felt by all citizens through consumption of material goods and use of public infrastructure. The proposed research program focuses on four sub topics that investigate the behaviour of HHEs at different scales of effect:
1) Impact initiation of HHEs: Impact by a high velocity projectile transmits a shock wave into the impacted material. If the material is energetic, chemical reaction will occur, possibly resulting in transition from fast burning to detonation. Explosive initiation by projectile impact is quantified by the shock pressure and volume of explosive material that is shocked with little curvature of the shock front. The presence of large fractions of heterogeneities modifies the sensitivity to shock, such that more of the shock front may produce detonation. Experimental ballistic impact tests are required to extend existing scaling laws to HHEs.
2) Detonation structure of HHEs: Ideal explosives detonate with a structure known as the Zel'dovichvon NeumannDöring (ZND) detonation: a strong inert shock that initiates chemical reaction, which progresses for a discrete amount of time and then stops. Solid explosive is converted into high temperature, high pressure gas that accelerates to sonic and then supersonic velocities soon after reaction completes. The large quantity and extreme mismatch of heterogeneities in HHEs can modify the detonation structure. Experimental measurements will be performed using time resolved free surface velocity measurement and impedance matching.
3) Modelling of particles in donation product flow: A critical factor governing the ability of HHEs to accelerate material is the energy transferred between the gaseous detonation products and solid particles in the flow. Multiphase simulations will be performed to elucidate this transfer.
4) Blast from HHEs: The presence of particles in the blast generated by an HHE historically complicated measurement of the impulse imparted at a distance from the charge. Novel laser velocimetry and spectroscopy techniques permit measurement of the complete impulse and enable correlation with exothermic reaction of the particles in air.