Grant: Alliance Grants
University of Toronto
$380,798.00
Mechanistic Understanding of Electrosynthesis for n-Propanol and Propylene from CO2
EF 2024-25
Résumé
The electrochemical synthesis of useful chemicals such as syngas, ethylene, and ethanol has seen significant progress in recent years. These advances hold promise for the electrification of chemical manufacturing and production of low-carbon intensity feedstocks. The production of C3 products n-propanol and propylene, however, has not seen similar progress, due to a poor understanding of a broader set of potential reaction pathways. In partnership with TotalEnergies, we will explore potential pathways to C3 products, and investigate the mechanisms of the reaction, and consider how these may lead to performance breakthroughs in terms of Faradaic efficiency. This project brings together a multidisciplinary team of researchers, encompassing chemical, mechanical, and materials engineers, from the University of Toronto and global industrial partner TotalEnergies. Leveraging computational modeling, experimental validation, and materials characterization, we aim to propel this technology forward and prepare it for demonstration, fostering the growth of a global market for made-in-Canada electrocatalytic systems tailored for electrochemical CO-to-C3 conversion.
Programme
Alliance Grants
Bénéficiaire
Emplacement
Ontario, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data
Tel que publié
Application id
592540-2023
Name nom
Sinton, David DA
Department département
Mechanical and Industrial Engineering
Organization id
31
Institution établissement
University of Toronto
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2024
Competition year année de concours
2023
Award amount
380798
Program id
ALLRP
Program name en
Alliance Grants
Program name fr
Subventions Alliance
Group en
RESEARCH PARTNERSHIPS
Group fr
PARTENARIATS DE RECHERCHE
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
305
Area of application group en
Energy resources
Area of application group fr
Ressources d'énergie
Area of application en
Energy storage and conversion
Area of application fr
Stockage et transformation de l'énergie
Research subject code
3401
Research subject group en
Physical chemistry
Research subject group fr
Chimie physique
Research subject en
Electrochemistry
Research subject fr
Électrochimie
Field of research list names en
Not available
Field of research list names fr
Non disponible
Socioeconomic objective list names en
Not available
Socioeconomic objective list names fr
Non disponible
Application title
Mechanistic Understanding of Electrosynthesis for n-Propanol and Propylene from CO2
Keywords
carbon dioxide; electrocatalysis; electrosynthesis; n-propanol; propylene; renewable chemicals
Application summary
The electrochemical synthesis of useful chemicals such as syngas, ethylene, and ethanol has seen significant progress in recent years. These advances hold promise for the electrification of chemical manufacturing and production of low-carbon intensity feedstocks. The production of C3 products n-propanol and propylene, however, has not seen similar progress, due to a poor understanding of a broader set of potential reaction pathways. In partnership with TotalEnergies, we will explore potential pathways to C3 products, and investigate the mechanisms of the reaction, and consider how these may lead to performance breakthroughs in terms of Faradaic efficiency. This project brings together a multidisciplinary team of researchers, encompassing chemical, mechanical, and materials engineers, from the University of Toronto and global industrial partner TotalEnergies. Leveraging computational modeling, experimental validation, and materials characterization, we aim to propel this technology forward and prepare it for demonstration, fostering the growth of a global market for made-in-Canada electrocatalytic systems tailored for electrochemical CO-to-C3 conversion.