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Grant: Strategic Projects - Group

Queen's University

$192,580.00

Thermally-regenerative fuel cell for transportation

EF 2010-11

Résumé
A typical internal combustion engine for a diesel transport truck converts about 30% of the fuel energy to moving the vehicle while 65% is lost as waste heat. We propose that this heat could be converted directly to electrical energy through a thermally regenerative fuel cell (TRFC). This device uses heat to remove hydrogen from a liquid compound and then recombines the hydrogen with the compound in a fuel cell to make electricity. It is a closed loop system in which the liquid compound and the hydrogen are continually recycled. The high electrical power loads in transports are, at present, satisfied by batteries supplied by the alternator. The relatively low efficiency of the alternator results in poor use of fuel for the electricity to the battery. Therefore, generation of electricity from the waste heat, using a TRFC, would increase fuel efficiency. Challenges in the project are both in chemistry and in engineering. The chemistry challenge is to identify a catalyst and a fluid that give very selective dehydrogenation (and subsequent rehydrogenation in the fuel cell), so that the fluid does not quickly degrade. The engineering challenges are the design of the fuel cell to handle the unconventional oxidant and the design of the rest of the system to ensure maximum heat collection and conversion to useable electricity. If successful, this low grade waste heat conversion system could find use in a number of wide ranging applications. Benefits to Canada would be increased fuel efficiency in trucks, development of uniquely Canadian energy-saving technology, and the training of HQP (4 graduate students, a postdoctoral fellow and a research associate).
Programme
Strategic Projects - Group
Bénéficiaire
Emplacement
Ontario, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data

Tel que publié

Application id
381116-2009
Name nom
Jessop, Philip
Department département
Chemistry
Organization id
29
Institution établissement
Queen's University
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2010
Competition year année de concours
2009
Award amount
192580
Program id
STPGP
Program name en
Strategic Projects - Group
Program name fr
Projets stratégiques - De groupe
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
1047
Committee name en
Strategic Projects Selection Panel - Energy
Committee name fr
Comité de sélection des projets stratégiques - Énergie
Area of application code
305
Area of application group en
Energy resources
Area of application group fr
Ressources d'énergie
Area of application en
Energy storage and conversion
Area of application fr
Stockage et transformation de l'énergie
Research subject code
3405
Research subject group en
Physical chemistry
Research subject group fr
Chimie physique
Research subject en
Catalysis, kinetics
Research subject fr
Catalyse et cinétique
Partie
2
Nb partie
3
Application title
Thermally-regenerative fuel cell for transportation
Keyword
NSERC
Application summary
A typical internal combustion engine for a diesel transport truck converts about 30% of the fuel energy to moving the vehicle while 65% is lost as waste heat. We propose that this heat could be converted directly to electrical energy through a thermally regenerative fuel cell (TRFC). This device uses heat to remove hydrogen from a liquid compound and then recombines the hydrogen with the compound in a fuel cell to make electricity. It is a closed loop system in which the liquid compound and the hydrogen are continually recycled. The high electrical power loads in transports are, at present, satisfied by batteries supplied by the alternator. The relatively low efficiency of the alternator results in poor use of fuel for the electricity to the battery. Therefore, generation of electricity from the waste heat, using a TRFC, would increase fuel efficiency. Challenges in the project are both in chemistry and in engineering. The chemistry challenge is to identify a catalyst and a fluid that give very selective dehydrogenation (and subsequent rehydrogenation in the fuel cell), so that the fluid does not quickly degrade. The engineering challenges are the design of the fuel cell to handle the unconventional oxidant and the design of the rest of the system to ensure maximum heat collection and conversion to useable electricity. If successful, this low grade waste heat conversion system could find use in a number of wide ranging applications. Benefits to Canada would be increased fuel efficiency in trucks, development of uniquely Canadian energy-saving technology, and the training of HQP (4 graduate students, a postdoctoral fellow and a research associate).