Grant: Collaborative Research and Development Grants
Queen's University
$140,000.00
Chemical aging of asphalt cement
EF 2009-10
Résumé
Our research objective is to develop an improved chemical aging protocol to better predict the relative field performance of straight and modified asphalt cements. The current rolling thin film oven (RTFO) and pressure aging vessel (PAV) methods fail to create laboratory-aged samples that perform similarly to materials recovered from the field.
The problem is best illustrated with a set of materials used in a 2003 trial on Highway 655 north of Timmins, Ontario. All materials in this trial are graded according to current standards in a narrow range between -34.6¯C and -37¯C. Hence, they were designed to survive and perform similarly with respect to thermal cracking during a cold spell of -34¯C after 7-10 years of service. This has not happened: only two sections survived largely unscathed and the remaining five sections showed serious damage after a cold spell of -34¯C in January 2004. Preliminary investigations of recovered asphalt cements from this trial have shown errors in the RTFO/PAV aging methods ranging from -2.8¯C to +12¯C. Such significant errors can help explain the observed variations in distress, with section 4 performing worst and section 1 performing best.
A more realistic aging method will be developed using very thin films hardened through oxidation, volatilization and exudation in moderate temperature and pressure conditions. Accompanying nanoindentation tests, applied directly to the aged films at low and ambient temperatures, will be developed for specification grading to more accurately reflect true performance in service. Canada will benefit from this research because our roads continue to suffer from premature thermal and fatigue cracking distress. The application of these research products by user agencies will allow them to save the taxpayers hundreds of millions of dollars.
Programme
Collaborative Research and Development Grants
Bénéficiaire
Emplacement
Ontario, Canada
Type de bénéficiaire
Academia
Type
Grant
Source
NSERC's Awards Data
Tel que publié
Application id
380759-2009
Name nom
Hesp, Simon
Department département
Chemistry
Organization id
29
Institution établissement
Queen's University
Province en
Ontario
Province fr
Ontario
Country en
CANADA
Country fr
CANADA
Fiscal year exercice financier
2009
Competition year année de concours
2009
Award amount
140000
Program id
CRDPJ
Program nane en
Collaborative Research and Development Grants
Program name fr
Subventions de recherche et développement coopérative
Group en
Research partnerships programs
Group fr
Programmes de partenariat
Committee code
96
Committee name en
RPP Internal Decision Cttee
Committee name fr
Cté de décision interne - PPR
Area of application code
602
Area of application group en
Construction, urban and rural planning
Area of application group fr
Construction, urbanisme et aménagement rural
Area of application en
Materials performance
Area of application fr
Performance des matériaux
Research subject code
2002
Research subject group en
Materials science and technology
Research subject group fr
Science et technologie des matériaux
Research subject en
Materials processing
Research subject fr
Transformation des matériaux
Partie
1
Nb partie
3
Application title
Chemical aging of asphalt cement
Keyword
NA
Application summary
Our research objective is to develop an improved chemical aging protocol to better predict the relative field performance of straight and modified asphalt cements. The current rolling thin film oven (RTFO) and pressure aging vessel (PAV) methods fail to create laboratory-aged samples that perform similarly to materials recovered from the field.
The problem is best illustrated with a set of materials used in a 2003 trial on Highway 655 north of Timmins, Ontario. All materials in this trial are graded according to current standards in a narrow range between -34.6¯C and -37¯C. Hence, they were designed to survive and perform similarly with respect to thermal cracking during a cold spell of -34¯C after 7-10 years of service. This has not happened: only two sections survived largely unscathed and the remaining five sections showed serious damage after a cold spell of -34¯C in January 2004. Preliminary investigations of recovered asphalt cements from this trial have shown errors in the RTFO/PAV aging methods ranging from -2.8¯C to +12¯C. Such significant errors can help explain the observed variations in distress, with section 4 performing worst and section 1 performing best.
A more realistic aging method will be developed using very thin films hardened through oxidation, volatilization and exudation in moderate temperature and pressure conditions. Accompanying nanoindentation tests, applied directly to the aged films at low and ambient temperatures, will be developed for specification grading to more accurately reflect true performance in service. Canada will benefit from this research because our roads continue to suffer from premature thermal and fatigue cracking distress. The application of these research products by user agencies will allow them to save the taxpayers hundreds of millions of dollars.